• 文献标题:   Microwave plasma based single step method for free standing graphene synthesis at atmospheric conditions
  • 文献类型:   Article
  • 作  者:   TATAROVA E, HENRIQUES J, LUHRS CC, DIAS A, PHILLIPS J, ABRASHEV MV, FERREIRA CM
  • 作者关键词:  
  • 出版物名称:   APPLIED PHYSICS LETTERS
  • ISSN:   0003-6951
  • 通讯作者地址:   Univ Tecn Lisboa
  • 被引频次:   30
  • DOI:   10.1063/1.4822178
  • 出版年:   2013

▎ 摘  要

Microwave atmospheric pressure plasmas driven by surface waves were used to synthesize graphene sheets from vaporized ethanol molecules carried through argon plasma. In the plasma, ethanol decomposes creating carbon atoms that form nanostructures in the outlet plasma stream, where external cooling/heating was applied. It was found that the outlet gas stream temperature plays an important role in the nucleation processes and the structural quality of the produced nanostructures. The synthesis of few layers (from one to five) graphene has been confirmed by high-resolution transmission electron microscopy. Raman spectral studies were conducted to determine the ratio of the 2D to G peaks (>2). Disorder D-peak to G-peak intensity ratio decreases when outlet gas stream temperature decreases. (C) 2013 AIP Publishing LLC.