• 文献标题:   Tailored sonochemical synthesis of V2O5 vertical bar graphene nanoplatelets composites and its enhanced Li-ion insertion properties
  • 文献类型:   Article
  • 作  者:   LIM DG, ZHAO YP, MANIKANDAN P, ADAMS RA, YOUNGBLOOD JP, POL VG
  • 作者关键词:   sonochemistry, v2o5 nanocrystalline, graphene, cathode, liion batterie
  • 出版物名称:   MATERIALS RESEARCH BULLETIN
  • ISSN:   0025-5408 EI 1873-4227
  • 通讯作者地址:   Purdue Univ
  • 被引频次:   1
  • DOI:   10.1016/j.materresbull.2019.02.014
  • 出版年:   2019

▎ 摘  要

Ultrasound-assisted surface modification of graphene nanoplatelets (GNPs) has made possible for in situ growth of V2O5 nanoparticles; homogeneously decorating inter-connected two-dimensional GNPs. The as-fabricated One-Step V2O5 vertical bar GNPs nanocomposite exhibited enhanced electronic conductivity and facilitates higher Li+ ion insertion/ extraction kinetics, attained the high capacity of 297 mA h g(-1) (10 mA g(-1)) corresponding to similar to 2 Li+ ion insertion/ extraction. Consequently, the sonochemically tailored One-Step V2O5 vertical bar GNPs nanocomposite delivered the specific capacity of 248 mA h g(-1) at 50 mA g(-1) with 83% capacity retention and 98.4% coulombic efficiency for the cycling studies. In addition, the rate capability studies were extended to One-Step V2O5 vertical bar GNPs cathode at different cm-rent density from 10 to 200 mA g(-1). On the other hand, the Two-Step (sonochemical synthesis of 200 nm V2O5 particles followed by its deposition on GNPs) V2O5 vertical bar GNPs composite cathode yielded less specific capacity of 225 mA h g(-1) (10 mA g(-1)) than the One-Step V2O5 vertical bar GNPs nanocomposite cathode.