• 文献标题:   Acetylene Black Loaded on Graphene as a Cathode Material for Boosting the Discharging Performance of Li/SOCl2 Battery
  • 文献类型:   Article
  • 作  者:   WEI JH, GAO XT, TAN SP, WANG F, ZHU XD, YIN GP
  • 作者关键词:   li/socl2 batterie, cathode, assembly, graphene, acetylene black
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:   Harbin Inst Technol
  • 被引频次:   3
  • DOI:   10.20964/2017.02.01
  • 出版年:   2017

▎ 摘  要

Lithium thionyl chloride (Li/SOCl2) battery is a promising primary battery owing to its highest theoretical working voltage (3.6 V), excellent output specific energy (up to 590 Wh/kg) and large working temperature interval. However, drawbacks such as insoluble product (LiCl) and non- fully dissolved sulfur deposited on the electrode will cause the failure of the full battery. Herein, we report a cathode material that can boost the discharging performance of Li/SOCl2 battery by facile assembly of acetylene black nanoparticles on graphene nanosheets. The resulting acetylene black/graphene hybrid exhibits an excellent discharging performance, delivering a capacity as high as 1706 mAh/g at a current density of 5 mA/cm(2).