• 文献标题:   A Facile Route to Controllable Synthesis of Fe3O4/Graphene Composites and Their Application in Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   FU CJ, ZHAO GG, ZHANG HJ, LI S
  • 作者关键词:   graphene, fe3o4, controllable synthesi, lithiumion battery, anode
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:   Heilongjiang Univ Sci Technol
  • 被引频次:   35
  • DOI:  
  • 出版年:   2014

▎ 摘  要

A facile and straightforward method has been developed to synthesize laminated-structured Fe3O4/graphene composite through solvothermal reaction. The particle size and coverage density of Fe3O4 on graphene sheets were controlled by adjusting the molar ratio of graphite oxide (GO) and Fe (II) ions. Spherical Fe3O4 nanoparticles were decorated densely and homogeneously on the graphene sheets. Galvanostatic charge-discharge cycling of the optimized Fe3O4/graphene composite exhibited a reversible specific capacity more than 963 mAh g(-1) after 100 cycles without detectable capacity fading at the current density of 100 mA g(-1). Even after 50 cycles at various rates from 100 to 2500 mA g(-1), it still maintained the specific capacity of 979 mAh g(-1) at 100 mA g(-1). The highly improved performance of Fe3O4/graphene composite could be attributed to the pinning effect of hydroxyl/epoxy groups on Fe atoms of Fe3O4 nanoparticles and the excellent interfacial interaction between Fe3O4 and graphene.