• 文献标题:   High-capacity Li2S-graphene oxide composite cathodes with stable cycling performance
  • 文献类型:   Article
  • 作  者:   SEH ZW, WANG HT, LIU N, ZHENG GY, LI WY, YAO HB, CUI Y
  • 作者关键词:  
  • 出版物名称:   CHEMICAL SCIENCE
  • ISSN:   2041-6520 EI 2041-6539
  • 通讯作者地址:   Stanford Univ
  • 被引频次:   73
  • DOI:   10.1039/c3sc52789a
  • 出版年:   2014

▎ 摘  要

With its high theoretical capacity of 1166 mA h g(-1), Li2S is a promising prelithiated cathode material for applications such as vehicle electrification and grid energy storage. Herein, we demonstrate facile synthesis of Li2S-graphene oxide composites for use as high-capacity and stable-cycling Li2S cathodes. The wrapping of graphene oxide onto the surface of Li2S through favorable lithium-oxygen interactions helps to minimize the dissolution of intermediate polysulfides into the electrolyte during cycling, which is a major reason for rapid capacity decay. Using the Li2S-graphene oxide composites as a cathode material, we demonstrate a high discharge capacity of 782 mA h g(-1) of Li2S (similar to 1122 mA h g(-1) of S) with stable cycling performance over 150 charge-discharge cycles.