▎ 摘　　要

Graphene fiber-based supercapacitors are known as the potential energy resources for wearable/flexible electronics. However, increasing their specific capacitance and energy density remains a significant challenge. This paper indicates a double layer capacitance of the graphene nanosheets accompanied by pseudocapacitive behavior of the polyaniline to prepare composite fibers with high capacitive response. The polyaniline/graphene composite fibers (PANI/GFs) were synthesized by the self-assembled strategy and chemical reduction by HI. The wrinkle architecture of graphene nanosheets and uniform dispersion of the polyaniline are beneficial to increase the internal electroactive sites and provide a stable structure for the composite fibers. The constructed fiber-shaped supercapacitors with solid-state electrolyte deliver an excellent areal specific capacitance of 370.2 mF cm(-2) and an outstanding areal energy density of 12.9 mu W h cm(-2). The current work reveals the attractive potential of the as-synthesized composite fibers for constructing fiber-shaped supercapacitors with distinguished electrochemical performance, which can be applied in future flexible electronics.