• 文献标题:   Mechanical and sodium ion conductivity properties of graphene oxide-incorporated nanocomposite polymer electrolyte membranes
  • 文献类型:   Article
  • 作  者:   KODURU HK, BRUNO L, MARINOV YG, HADJICHRISTOV GB, SCARAMUZZA N
  • 作者关键词:   nanocomposite polymer electrolyte membrane, differential scanning calarometric studie, mechanical stressstrain measurement, complex electrical impedance dielectric studie
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:   Univ Calabria
  • 被引频次:   2
  • DOI:   10.1007/s10008-019-04359-6
  • 出版年:   2019

▎ 摘  要

Graphene oxide (GO) nano-sheets incorporated PEO/PVA composite membranes complexed with NaIO4 salt at different concentrations were prepared using the solution casting technique. The nanocomposite PEO/PVA membranes demonsrated improved mechanical tensile strength and Young's modulus in comparision to pure PEO/PVA blends. Impedance measurements were performed in the frequency range of 0.1 Hz-3 MHz and at temperature in the range of 30-70 degrees C. The pure blend electrolyte complexed with 20 wt.% of NaIO4 salt demonstrated Na+ ion conductivity of 1.03 x 10(-7) S/cm at room temperature. Comparatively, PEO/PVA/NaIO4 (20 wt.%) blend electrolyte membranes demonstrated one order increment in room temperature ionic conductivity as a result of incorporation of 0.9 wt.% GO nano-sheets. The effect of introducing GO nano-sheets in the matrix of PEO/PVA blend electrolyte membranes was noticed by means of increment in charge carriers, diffusivity and mobility of the ions.