• 文献标题:   A New Class of Polyethylene Glycol-Grafted Graphene Carbon Nanotube Composite as a Selective Adsorbent for Au(III)
  • 文献类型:   Article, Early Access
  • 作  者:   KHAN A, HUSSEIN MA, ALSHERI FM, ALAMRY KA, ASIRI AM
  • 作者关键词:   au iii detection, mixed g/cnt, polyethylene glycol, surface selectivity, adsorption capacity, adsorption isotherm
  • 出版物名称:   WASTE BIOMASS VALORIZATION
  • ISSN:   1877-2641 EI 1877-265X
  • 通讯作者地址:   King Abdulaziz Univ
  • 被引频次:   0
  • DOI:   10.1007/s12649-020-01053-x EA APR 2020
  • 出版年:  

▎ 摘  要

A new class of polyethylene glycol/graphene/carbon nanotube (PEG/G/CNTa-e) composites were prepared using a simple dissolution process, with ultrasonic assistance. Mixed G/CNT, with variable loadings, have been utilized as reinforcements for a PEG polymer matrix, to produce a new class of nanocomposite materials. The PEG/G/CNT composite was characterized using various spectroscopic techniques, such as Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM), to identify various bonds and to confirm the structure of the materials. To understand the potentiality of the material, the selectivity of PEG/G/CNT towards different metal ions, including Au(III), Y(III), Pb(II), Zn(II), Cu(II), Ni(II), Fe(III), Cr(III), and Co(II), was evaluated. The selectivity of the PEG/G/CNT e-phase was strongest towards Au(III). PEG/G/CNT was utilized as a particle extractor for Au(III) discovery in watery media. The static adsorption limit of PEG/G/CNT for Au(III) was determined to be 80.80 mg/g. The results of the adsorption isothermal assay additionally affirmed the legitimacy of the Langmuir isotherm model for the adsorption procedure. In addition, the productivity of recently incorporated materials was examined for the specific extraction of Au(III), using inductively coupled plasma-optical emission spectrometry (ICP-OES). This PEG/G/CNTa-e material can be used for the extraction of gold from the abundantly minerals.