• 文献标题:   Silver Decorated Reduced Graphene Oxide as Electrocatalyst for Zinc-Air Batteries
  • 文献类型:   Article
  • 作  者:   POOLNAPOL L, KAOIAN W, SOMWANGTHANAROJ A, MAHLENDORF F, NGUYEN MT, YONEZAWA T, KHEAWHOM S
  • 作者关键词:   oxygen reduction, air cathode, zincair battery, silver, graphene, current density
  • 出版物名称:   ENERGIES
  • ISSN:  
  • 通讯作者地址:   Chulalongkorn Univ
  • 被引频次:   7
  • DOI:   10.3390/en13020462
  • 出版年:   2020

▎ 摘  要

Due to their low cost and very high energy density, zinc-air batteries (ZABs) exhibit high potential for various energy applications. The electrochemical performance of the air-cathode has a decisive impact on the discharge performance of ZABs because the sluggish oxygen reduction reaction (ORR) kinetics increase the overpotential of the air-cathode and hence the performance of ZABs. In this work, reduced graphene oxide decorated with silver nanoparticles (AgNP/rGO) is synthesized using simultaneous reduction of graphene oxide and silver ions. Different amounts of silver loading are examined for the synthesis of AgNP/rGO. The synthesized AgNP/rGO samples are analyzed using a rotating disk electrode in order to investigate ORR activity. Then, the synthesized AgNP/rGO electrocatalyst is applied on a tubular designed zinc-air battery in order to study the performance of the zinc-air battery. Results demonstrate that AgNP/rGO is an efficient and cost-effective ORR electrocatalyst for its practical application in ZABs.