• 文献标题:   One-pot preparation of graphene oxide magnetic nanocomposites for the removal of tetrabromobisphenol A
  • 文献类型:   Article
  • 作  者:   JI LQ, BAI X, ZHOU LC, SHI HC, CHEN W, HUA ZL
  • 作者关键词:   magnetic, graphene oxide go, adsorption, tetrabromobisphenol a tbbpa
  • 出版物名称:   FRONTIERS OF ENVIRONMENTAL SCIENCE ENGINEERING
  • ISSN:   2095-2201 EI 2095-221X
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   15
  • DOI:   10.1007/s11783-013-0515-2
  • 出版年:   2013

▎ 摘  要

A simple solvothermal method was used to prepare monodisperse magnetite (Fe3O4) nanoparticles attached onto graphene oxide (GO) sheets as adsorbents to remove tetrabromobisphenol A (TBBPA) from an aqueous solution. These Fe3O4/GO (MGO) nanocomposites were characterized by transmission electron microscopy. The adsorption capacity at different initial pH, contact duration, and temperature were evaluated. The kinetics of adsorption was found to fit the pseudo-second-order model perfectly. The adsorption isotherm well fitted the Langmuir model, and the theoretical maximum of adsorption capacity calculated by the Langmuir model was 27.26 mg center dot g(-1). The adsorption thermodynamics of TBBPA on the MGO nanocomposites was determined at 303 K, 313 K, and 323 K, respectively. The results indicated that the adsorption was spontaneous and endothermic. The MGO nanocomposites were conveniently separated from the media by an external magnetic field within several seconds, and then regenerated in 0.2M NaOH solution. Thus, the MGO nanocomposites are a promising candidate for TBBPA removal from wastewater.