• 文献标题:   Dahlia-liked Carbon Nanohorns Decorated Graphene/Polyaniline Nanocomposite and Its Derived Nitrogen-doped Carbon for High-performance Supercapacitor
  • 文献类型:   Article
  • 作  者:   LU QF, WANG SH, ZHOU J, DUAN FF, YANG HJ, LIU R
  • 作者关键词:   dahlialiked carbon nanohorn, spacer, nanotechnology, electrochemistry, asymmetric supercapacitor
  • 出版物名称:   CHEMISTRYSELECT
  • ISSN:   2365-6549
  • 通讯作者地址:   Fuzhou Univ
  • 被引频次:   0
  • DOI:   10.1002/slct.201901553
  • 出版年:   2019

▎ 摘  要

A dahlia-liked carbon nanohorns (CNHs) decorated graphene/polyaniline (CGP) nanocomposite was prepared via in situ chemical oxidation and hydrazine hydrate reducing. Firstly, dahlia-liked CNHs decorated graphene oxide/polyaniline (CGOP) composite was synthesized from the polymerization of aniline monomers on the surface of graphene oxide with spherical dahlia-liked carbon nanohorns as spacers. Then, the CGP composite was obtained by reducing CGOP using hydrazine hydrate. CGP exhibited a uniform three-dimensional nanostructure because long cone-shaped tips of dahlia-liked CNHs spacers can boost the isolation effect of the nanocomposite. The maximum specific capacitance of CGP was up to 769 F g(-1) at a current density of 1 A g(-1) when served as supercapacitors electrodes. Importantly, CGP also performed a good rate capability and high stability. Furthermore, a CGP-based asymmetric supercapacitor was assembled and delivered an energy density of 19.1 Wh kg(-1) at a power density of 1504.9 W kg(-1).