• 文献标题:   Measuring quantum conductance and capacitance of graphene using impedance-derived capacitance spectroscopy
  • 文献类型:   Article
  • 作  者:   LOPES LC, SANTOS A, BUENO PR
  • 作者关键词:   graphene, quantum capacitance, quantum conductance, impedance spectroscopy, nanoscale electrochemistry
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:  
  • 被引频次:   4
  • DOI:   10.1016/j.carbon.2021.08.055 EA SEP 2021
  • 出版年:   2021

▎ 摘  要

Here, we demonstrate that impedance-derived capacitance spectroscopy is a useful method for measuring and analyzing the quantum of conductance and capacitance of a single-layer graphene sheet. Both quantum conductance and capacitance exhibit the expected traditional V-shape when measured as a function of bias potential (with the minima of both parameters being at the Dirac point) in a 1-Butyl-3methylimidazolium tetrafluoroborate ionic liquid environment. Measurements were conducted at a specific low-frequency limit in which the conductance and capacitance were scanned as a function of bias potential to attain the quantum conductive and capacitive V-shapes. The V-shapes agree in terms of magnitude and profile with those reported in the literature using different methodologies and/or techniques. This validates impedance-derived capacitance spectroscopy as a suitable method to acquire key information of graphene and its derivatives. This method represents an alternative for rapid construction of both conductive and capacitive V-shapes of graphene in a single, simple experimental run. (c) 2021 Elsevier Ltd. All rights reserved.