• 文献标题:   Superior catalytic performances of platinum nanoparticles loaded nitrogen-doped graphene toward methanol oxidation and hydrogen evolution reaction
  • 文献类型:   Article
  • 作  者:   LIU D, LI LB, YOU TY
  • 作者关键词:   nitrogendoped, graphene, pt nanoparticle, methanol oxidation, hydrogen evolution reaction
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797 EI 1095-7103
  • 通讯作者地址:   Jiangsu Univ
  • 被引频次:   40
  • DOI:   10.1016/j.jcis.2016.10.038
  • 出版年:   2017

▎ 摘  要

The catalysts with excellent catalytic properties and low-cost are still highly desirable in many fields, such as fuel cells. In respect of this challenge, we have synthesized high-quality platinum nanoparticles loaded nitrogen-doped graphene (Pt/NG) by using formic acid as reduction agent and commercial available nitrogen-doped graphene (N-graphene) as supporting materials. The morphology and component characterization demonstrate that high-loading Pt nanoparticles with a mean diameter of 2.5 nm were uniformly dispersed on nitrogen-doped graphene. The resulting Pt/NG exhibit higher catalytic activity toward methanol oxidation and hydrogen evolution reaction compared with commercial Pt/C or self-synthesized platinum nanoparticles-loaded graphene. The superior catalytic performance of Pt/NG are discussed, and ascribed to the well-dispersed Pt nanoparticles and abundant edge plane sites on N-graphene. The resultant Pt/NG with high catalytic properties and cost-effective may emerge as a promising high-performance catalyst for fuel cells. (C) 2016 Published by Elsevier Inc.