• 文献标题:   Enhanced electrochemical properties of graphene-wrapped ZnMn2O4 nanorods for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   ZHENG ZM, CHENG YL, YAN XB, WANG RT, ZHANG P
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   65
  • DOI:   10.1039/c3ta13511j
  • 出版年:   2014

▎ 摘  要

Thermally reduced graphene oxide (rGO)-wrapped ZnMn2O4 nanorods have been successfully fabricated via a facile bottom-up approach. Characterization results show that porous ZnMn2O4 nanorods are uniformly wrapped by ultrathin rGO sheets. The unique structure of this rGO-ZnMn2O4 composite could facilitate both ion and electron diffusion, thus providing suitable characteristics of an anode material for high performance lithium-ion batteries. Specifically, the conductive rGO sheets could act as an efficient buffer to relax the volume changes from Li+ insertion/extraction, and enable the structural and interfacial stabilization of ZnMn2O4 crystals. As a consequence, a high and stable reversible capacity (707 mA h g(-1) at 100 mA g(-1) over 50 cycles) and an excellent rate capability (440 mA h g(-1) at 2000 mA g(-1)) are achieved with this composite material.