• 文献标题:   Coercivity enhancement by low oxygen content graphene addition in hot-deformed Nd-Fe-B
  • 文献类型:   Article
  • 作  者:   YANG QS, WANG RQ, LIU Y, LI J, CHEN HX, YANG XJ
  • 作者关键词:   ndfeb, hotdeformation, low oxygen content graphene nanoplatelet, microstructure, coercivity
  • 出版物名称:   JOURNAL OF MAGNETISM MAGNETIC MATERIALS
  • ISSN:   0304-8853 EI 1873-4766
  • 通讯作者地址:   Sichuan Univ
  • 被引频次:   0
  • DOI:   10.1016/j.jmmm.2020.166940
  • 出版年:   2020

▎ 摘  要

The effects of oxygen content in graphene nanoplatelets (GNPs) on the microstructure and magnetic properties of hot-deformed (HDed) Nd-Fe-B magnets were investigated in this work. The GNPs were heat treated at 500 degrees C to effectively reduce the oxygen content from 27000 ppm (GNP-R) to 7768 ppm (GNP-H). Compared with adding the same amount of GNP-R, the GNP-H doped magnet possessed finer and better texture grains at the contact interface of original powders. The coercivity of GNP-H doped magnet was enhanced from 14.16 kOe to 16.62 kOe, and the remanence increased from 13.18 kGs to 13.61 kGs. Owing to the high thermal conductivity of GNP-H doped magnet, the heat transferred between the grains more quickly and thus restraining the grain growth. Therefore, the GNP-H doped magnet got a higher coercivity. The observation of microstructure revealed that the adsorbed oxygen on the surface of GNP-R reacted with Nd-rich phase. It would result in the oxidation of Nd-rich phase and the decreasing of Nd-rich phase at the grain boundaries. Because of inadequate liquid Nd-rich phase, the Nd2Fe14B grains were difficult to complete the dissolution-reprecipitation. Consequently, a high oxygen environment would deteriorate the orientation of grains.