• 文献标题:   Graphene oxide modified with carboxymethyl cellulose for high adsorption capacities towards Nd(III) and Ce(III) from aqueous solutions
  • 文献类型:   Article
  • 作  者:   ABDELHAMID AI, ABU ELGOUD EM, ALY HF
  • 作者关键词:   graphene oxide, sodium carboxymethyl cellulose, composite, cerium, neodymium, adsorption
  • 出版物名称:   CELLULOSE
  • ISSN:   0969-0239 EI 1572-882X
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1007/s10570-022-04862-6 EA OCT 2022
  • 出版年:   2022

▎ 摘  要

This work addresses a simple method to functionalize graphene oxide with sodium carboxymethyl cellulose using tetraethyl orthosilicate as a linker for rapid and significant removal of Nd(III) and Ce(III) from aqueous solutions. The prepared composite (GO-CMC) was characterized by different techniques to confirm the modification and adsorption process. The sorption performance of the GO-CMC was evaluated using Nd(III) and Ce(III) as absorbent materials. The experimental results demonstrated that the sorption process was excellently fitted by the pseudo-second-order kinetic model. The adsorption results were also analyzed by different isotherm models. According to the Langmuir isotherm model, the experimental sorption capacities at pH 3.0 was 661.21 and 436.55 mg/g for Nd(III) and Ce(III), respectively. The thermodynamic results indicated that the sorption process of the two examined metal ions was endothermic and spontaneous. The regenerated GO-CMC composite has a similar removal percentage to the original composite. These results confirmed that the prepared composite (GO-CMC) could be used as an effective adsorbent for Nd(III) and Ce(III) from certain multielement solutions.