• 文献标题:   Crown Ether Grafted Graphene Oxide/Chitosan/Polyvinyl Alcohol Nanofiber Membrane for Highly Selective Adsorption and Separation of Lithium Ion
  • 文献类型:   Article
  • 作  者:   ZHENG XD, LI A, HUA J, ZHANG YZ, LI ZY
  • 作者关键词:   crown ether grafting, selective adsorption, composite membrane
  • 出版物名称:   NANOMATERIALS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   9
  • DOI:   10.3390/nano11102668
  • 出版年:   2021

▎ 摘  要

Nanofiber membranes were successfully prepared with crown ether (CE) functionalized graphene oxide (GO), chitosan (CS), and polyvinyl alcohol (PVA) by low-temperature thermally induced liquid-liquid phase separation. The physical and chemical properties and adsorption performance of nanofiber membrane were studied through SEM, FT-IR, XRD, and static adsorption experiments. The results show that the specific surface area of the nanofiber membrane is as high as 101.5 m(2)center dot g(-1). The results of static adsorption experiments show that the maximum adsorption capacity of the nanofiber membrane can reach 168.50 mg center dot g(-1) when the pH is 7.0. In the selective adsorption experiment, the nanofiber membrane showed high selectivity for Li+ in salt lake brine. After five cycles, the material still retains 88.31% of the adsorption capacity. Therefore, it is proved that the material has good regeneration ability.