• 文献标题:   Synthesis and characterization of amine functionalized graphene oxide and scope as catalyst for Knoevenagel condensation reaction
  • 文献类型:   Article
  • 作  者:   RANA S, JONNALAGADDA SB
  • 作者关键词:   graphene oxide, amine functionalized graphene oxide, knoevenagel condensation, cinnamic acid, recyclable catalyst
  • 出版物名称:   CATALYSIS COMMUNICATIONS
  • ISSN:   1566-7367 EI 1873-3905
  • 通讯作者地址:   Univ KwaZulu Natal
  • 被引频次:   34
  • DOI:   10.1016/j.catcom.2016.12.023
  • 出版年:   2017

▎ 摘  要

Novel amine modified graphene oxide (APTES-GO) was prepared using organo silane (aminopropyltrimethoxysilane, APTES) and the material was fully characterized by PXRD, Raman, SEM, FTIR, and TEM: Successful grafting of the amine group over the graphene oxide (GO) surface was confirmed by FT-IR and TEM data. APTES-GO as heterogeneous catalyst demonstrated impressive activity for solvent-free Knoevenagel condensation reaction producing cinnamic acid with excellent conversion (94%) and selectivity (99%) at RT. The catalytic activity remained almost unchanged for four cycles and in fifth cycle conversion was 9% less. (C) 2016 Elsevier B.V. All rights reserved.