• 文献标题:   Electrochemical Gate-Controlled Charge Transport in Graphene in Ionic Liquid and Aqueous Solution
  • 文献类型:   Article
  • 作  者:   CHEN F, QING Q, XIA JL, LI JH, TAO NJ
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  • ISSN:   0002-7863
  • 通讯作者地址:   Arizona State Univ
  • 被引频次:   171
  • DOI:   10.1021/ja9041862
  • 出版年:   2009

▎ 摘  要

We have studied the electron transport behavior of electrochemically gated graphene transistors in different solutions. In an ionic liquid, we have determined the electron and hole carrier densities and estimated the concentration of charged impurities to be (1-10) x 10(12) cm(-2). The minimum conductivity displays an exponential decrease with the density of charged impurities, which is attributed to the impurity scattering of the carriers. In aqueous solutions, the position of minimum conductivity shifts negatively as the ionic concentration increases. The dependence of the transport properties on ionic concentration is important for biosensor applications, and the observation is modeled in terms of screening for impurity charges by the ions in solutions.