• 文献标题:   Poly(anthraquinonylimide)/graphene composite cathode for sodium-ion batteries
  • 文献类型:   Article
  • 作  者:   ZHANG H, WANG HT, CAO SA, LI T, XU F
  • 作者关键词:   polymer, composite material, polymeric composite, energy storage, conversion
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:   Wuhan Univ
  • 被引频次:   0
  • DOI:   10.1016/j.matlet.2020.127596
  • 出版年:   2020

▎ 摘  要

Organic compounds are promising alternatives to inorganic materials as sodium-storage materials. Typically, conjugated carbonyl polymers attract the most attention due to the multiple redox sites and structure variety, but the low conductivity is hindering their application. In the present study, a poly(a nthraquinonylimide)@graphene composite (PAQI@G) is prepared via a one-step solvothermal process, where the PAQI flakes are in well-contact with graphene. The graphene provides a conductive matrix facilitating electric conduction and a stable framework to maintain the material integrity. The PAQI@G cathode exhibits an outstanding rate capability with a capacity of 85 mAh g(-1) at 1000 mA g(-1) and an excellent cycleability with 95% capacity retention over 1500 cycles. The present work offers simple strategies for exploration of sustainable and high-performance organic materials for sodium-ion batteries. (C) 2020 Elsevier B.V. All rights reserved.