• 文献标题:   Potentiometric ion-selective sensors based on UV-ozone irradiated laser-induced graphene electrode
  • 文献类型:   Article
  • 作  者:   CHOUDHURY S, ROY S, BHATTACHARYA G, FISHLOCK S, DESHMUKH S, BHOWMICK S, MCLAUGHLIGN J, ROY SS
  • 作者关键词:   laserinduced graphene, ionselective membrane, wearable electrode, electrochemical analysi, sweat sensor
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:  
  • 被引频次:   10
  • DOI:   10.1016/j.electacta.2021.138341 EA MAY 2021
  • 出版年:   2021

▎ 摘  要

Disposable devices for sensing biomarkers like Na+ ion in sweat was developed using UV-Ozone irradiated laser-induced graphene (LIG) based electrodes. Solid-state ion-selective electrodes (ISEs) sensitive to Na+ ions were fabricated by a two-step drop-coating process of polyvinyl chloride solution containing plasticizer, ionophore and ion-exchanger on LIG electrode. Hydrophobic to hydrophilic transition induced by UV-Ozone treatment reduced the contact angle, resulting in better permeation of the ion-selective membrane into the ozonized LIG film. Raman spectroscopy and IR absorption studies indicate physisorption of ozone on LIG. Performance of ozonized LIG (O-LIG) electrodes was much better than pristine LIG and screen-printed carbon electrodes. Sensitivity of 60.2 +/- 0.9 mV/ decade to Na+ ions and a lower limit of detection of 1 x 10(-6) M was achieved using O-LIG based ISEs. Response time of the devices were around 1 min. (c) 2021 Elsevier Ltd. All rights reserved.