• 文献标题:   Electrochemically Reduced Graphene Oxide as Modified Electrode Material for Determination of Dihydroxybenzenes
  • 文献类型:   Article
  • 作  者:   WANG MM, LI X, LIU J, XU WJ, DONG YL, LIU P, ZHANG CC
  • 作者关键词:   graphene, electrochemical reduction, dihydroxybenzene, simultaneous determination
  • 出版物名称:   JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGYMATERIALS SCIENCE EDITION
  • ISSN:   1000-2413 EI 1993-0437
  • 通讯作者地址:   Wuhan Univ Technol
  • 被引频次:   2
  • DOI:   10.1007/s11595-017-1734-3
  • 出版年:   2017

▎ 摘  要

A simple and green method was introduced to fabricate the electrochemical sensor based on the electrochemically reduced graphene oxide (ERGO) modified electrode. It was found that the ERGO modified electrode exhibited an excellent catalytic activity toward the oxidation of dihydroxybenzenes isomers. Under the optimum conditions, in the simultaneous determination of the dihydroxybenzene isomers, the currents were linear with the concentrations of the isomers from 5 to 550 mu mol/L for hydroquinone (HQ), from 6 to 400 ae mol/L for catechol (CT) and from 5 to 350 mu mol/L for resorcinol (RS), respectively. In addition, the proposed sensor has good stability and reproducibility. The developed method has been applied to the simultaneous determination of dihydroxybenzene isomers in real samples with a satisfactory recovery from 98% to 103%.