• 文献标题:   Functionalized graphene oxide with ethylenediamine and 1,6-hexanediamine
  • 文献类型:   Article
  • 作  者:   YAN JL, CHEN GJ, CAO J, YANG W, XIE BH, YANG MB
  • 作者关键词:   graphene, graphene oxide, aminofunctionalization, diamine
  • 出版物名称:   NEW CARBON MATERIALS
  • ISSN:   1007-8827
  • 通讯作者地址:   Sichuan Univ
  • 被引频次:   76
  • DOI:   10.1016/S1872-5805(12)60022-5
  • 出版年:   2012

▎ 摘  要

Graphene oxide (GO) obtained by Hummers method was functionalized by ethylenediamine (EA) and 1,6-hexanediamine (HA) in N, N-dimethyl formamide using 1, 1, 3, 3-tetramethy-luronium hexafluorophosphate as a coupling agent. The functionalized GO was characterized by elemental analysis, FT-IR, XRD, XPS, TGA, SEM and TEM. Results showed one carbon atom in nine to ten of the carbon atoms in GO was functionalized by an amine group. The thermal stability of the GO functionalized by HA was much higher than the one functionalized by EA. However, the former was less dispersible in N, N-dimethyl formamide than the latter.