• 文献标题:   Preparation of Gold Nanoparticle/Graphene Composites with Controlled Weight Contents and Their Application in Biosensors
  • 文献类型:   Article
  • 作  者:   HONG WJ, BAI H, XU YX, YAO ZY, GU ZZ, SHI GQ
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447 EI 1932-7455
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   349
  • DOI:   10.1021/jp9101724
  • 出版年:   2010

▎ 摘  要

Positively charged gold nanoparticles (GNPs) with diameters of 2-6 nm were self-assembled onto the surfaces of 1-pyrene butyric acid functionalized graphene (PFG) sheets simply by mixing their aqueous dispersions. The amount of GNPs assembled on PFG sheets can be easily modulated by controlling the feeding weight ratio of both components. Furthermore, it was found that PFG sheets had a high loading capability of GNPs, and the maximum value was determined to be about 300 times the PFG's own weight. Glassy carbon (GC) electrodes modified with the composite of GNPs and PFG (GNP-PFG composite) showed strong electrocatalytic activity and high electrochemical stability. A uric acid electrochemical sensor based on the composite modified electrode exhibited rapid response and high sensitivity.