• 文献标题:   One-step synthesis of nickel sulfide/N-doped graphene composite as anode materials for lithium ion batteries
  • 文献类型:   Article
  • 作  者:   TAO HC, YANG XL, ZHANG LL, NI SB
  • 作者关键词:   lithium ion batterie, anode, nickel sulfide, ndoped graphene, onestep
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   China Three Gorges Univ
  • 被引频次:   28
  • DOI:   10.1016/j.jelechem.2014.10.035
  • 出版年:   2015

▎ 摘  要

Nickel sulfide/N-doped graphene composite as high performance anode materials has been synthesized through a simultaneous hydrothermal method. The morphology, structure and electrochemical performance of nickel sulfide/N-doped graphene composite were investigated by field emission scanning electron microscopy, transmission electron microscope, X-ray diffraction, Raman spectra, Fourier transform infrared spectra, X-ray photoelectron spectroscopy and electrochemical measurements. The nickel sulfide with a length of about 500 nm and diameter of 100 nm clung to the N-doped graphene matrix. The nickel sulfide/N-doped graphene composite exhibits a relatively high reversible capacity and good cycling stability as anode materials for lithium ion batteries. The good electrochemical performance can be attributed to N-doped graphene, which improves the electronic conductivity of composite and suppresses the volume effect as elastic matrix. The one-dimensional structure of nickel sulfide facilitates the diffusion of lithium ions and electrons. (C) 2014 Elsevier B.V. All rights reserved.