• 文献标题:   ZnO nanoparticles anchored on nitrogen and sulfur co-doped graphene sheets for lithium-ion batteries applications
  • 文献类型:   Article
  • 作  者:   YANG CN, QING YQ, AN K, CHEN JZ, TAN JY, ZHANG ZF, WANG LS, LIU CS
  • 作者关键词:   graphene, anode, lithiumion batterie, zno
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:   Northeastern Univ
  • 被引频次:   3
  • DOI:   10.1007/s11581-018-2555-x
  • 出版年:   2018

▎ 摘  要

Herein, we demonstrate a facile one-step hydrothermal synthesis route to anchor ZnO nanoparticles on nitrogen and sulfur co-doped graphene sheets. The detailed material and electrochemical characterization have been carried out to demonstrate the potential of novel ZnO/NSG nanocomposite in Li-ion battery (LIBs) applications. The structure and morphology of nanocomposite were assessed by X-ray diffraction (XRD), Fourier transform infrared (FTIR), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The as-synthesized ZnO/NSG nanocomposite has been studied as anode material in LIBs and delivered a high initial discharge capacity of 1723mAhg(-1), at the current density of 200mAg(-1). After 100cycles, the ZnO/NSG nanocomposites demonstrated a high reversible capacity of 720mAhg(-1) and coulombic efficiency of 99.8%, which can be attributed to the porous three-dimensional network, constructed by ZnO nanoparticles and nitrogen and sulfur co-doped graphene. Moreover, the designed nanocomposite has shown excellent rate capability and lower charge transfer resistance. These results are promising and encourage further research in the area of ZnO-based anodes for next-generation LIBs.