• 文献标题:   Three-Dimensional Sulfur/Graphene Multifunctional Hybrid Sponges for Lithium-Sulfur Batteries with Large Areal Mass Loading
  • 文献类型:   Article
  • 作  者:   LU ST, CHEN Y, WU XH, WANG ZD, LI Y
  • 作者关键词:  
  • 出版物名称:   SCIENTIFIC REPORTS
  • ISSN:   2045-2322
  • 通讯作者地址:   Harbin Inst Technol
  • 被引频次:   139
  • DOI:   10.1038/srep04629
  • 出版年:   2014

▎ 摘  要

In this communication, we introduce the concept of three dimensional (3D) battery electrodes to enhance the capacity per footprint area for lithium-sulfur battery. In such a battery, 3D electrode of sulfur embedded into porous graphene sponges (S-GS) was directly used as the cathode with large areal mass loading of sulfur (12 mg cm(-2)), approximately 6-12 times larger than that of most reports. The graphene sponges (GS) worked as a framework that can provide high electronic conductive network, abilities to absorb the polysulfides intermediate, and meanwhile mechanical support to accommodate the volume changes during charge and discharge. As a result, the S-GS electrode with 80 wt.% sulfur can deliver an extremely high areal specific capacitance of 6.0 mAh cm(-2) of the 11th cycle, and maintain 4.2 mAh cm(-2) after 300 charge-discharge cycles at a rate of 0.1C, representing an extremely low decay rate (0.08% per cycle after 300 cycles), which could be the highest areal specific capacity with comparable cycle stability among the rechargeable Li/S batteries reported ever.