• 文献标题:   Graphene Growth Directly on SiO2/Si by Hot Filament Chemical Vapor Deposition
  • 文献类型:   Article
  • 作  者:   RODRIGUEZVILLANUEVA S, MENDOZA F, INSTAN AA, KATIYAR RS, WEINER BR, MORELL G
  • 作者关键词:   graphene, hot filament chemical vapor deposition, copper catalytic effect
  • 出版物名称:   NANOMATERIALS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.3390/nano12010109
  • 出版年:   2022

▎ 摘  要

We report the first direct synthesis of graphene on SiO2/Si by hot-filament chemical vapor deposition. Graphene deposition was conducted at low pressures (35 Torr) with a mixture of methane/hydrogen and a substrate temperature of 970 degrees C followed by spontaneous cooling to room temperature. A thin copper-strip was deposited in the middle of the SiO2/Si substrate as catalytic material. Raman spectroscopy mapping and atomic force microscopy measurements indicate the growth of few-layers of graphene over the entire SiO2/Si substrate, far beyond the thin copper-strip, while X-ray photoelectron spectroscopy and energy-dispersive X-ray spectroscopy showed negligible amounts of copper next to the initially deposited strip. The scale of the graphene nanocrystal was estimated by Raman spectroscopy and scanning electron microscopy.