• 文献标题:   Graphene grown on stainless steel as a high-performance and ecofriendly anti-corrosion coating for polymer electrolyte membrane fuel cell bipolar plates
  • 文献类型:   Article
  • 作  者:   PU NW, SHI GN, LIU YM, SUN XL, CHANG JK, SUN CL, GER MD, CHEN CY, WANG PC, PENG YY, WU CH, LAWES S
  • 作者关键词:   graphene, stainless steel, corrosion, passivation, coating
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Natl Def Univ
  • 被引频次:   65
  • DOI:   10.1016/j.jpowsour.2015.02.055
  • 出版年:   2015

▎ 摘  要

In this study, the growth of graphene by chemical vapor deposition (CVD) on SUS304 stainless steel and on a catalyzing Ni/SUS304 double-layered structure was investigated. The results indicated that a thin and multilayered graphene film can be continuously grown across the metal grain boundaries of the Nil SUS304 stainless steel and significantly enhance its corrosion resistance. A 3.5 wt% saline polarization test demonstrated that the corrosion currents in graphene-covered SUS304 were improved fivefold relative to the corrosion currents in non-graphene-covered SUS304. In addition to enhancing the corrosion resistance of stainless steel, a graphene coating also ameliorates another shortcoming of stainless steel in a corrosive environment: the formation of a passive oxidation layer on the stainless steel surface that decreases conductivity. After a corrosion test, the graphene-covered stainless steel continued to exhibit not only an excellent low interfacial contact resistance (ICR) of 36 m Omega cm(2) but also outstanding drainage characteristics. The above results suggest that an extremely thin, lightweight protective coating of graphene on stainless steel can act as the next-generation bipolar plates of fuel cells. (C) 2015 Elsevier B.V. All rights reserved.