• 文献标题:   Phonon-Assisted Electroluminescence from Metallic Carbon Nanotubes and Graphene
  • 文献类型:   Article
  • 作  者:   ESSIG S, MARQUARDT CW, VIJAYARAGHAVAN A, GANZHORN M, DEHM S, HENNRICH F, OU F, GREEN AA, SCIASCIA C, BONACCORSO F, BOHNEN KP, VON LOHNEYSEN H, KAPPES MM, AJAYAN PM, HERSAM MC, FERRARI AC, KRUPKE R
  • 作者关键词:   carbon nanotube, graphene, electroluminescence, phonon
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Karlsruhe Inst Technol
  • 被引频次:   56
  • DOI:   10.1021/nl9039795
  • 出版年:   2010

▎ 摘  要

We report on light emission from biased metallic single-wall carbon nanotube (SWNT), multiwall carbon nanotube (MWNT) and few-layer graphene (FLG) devices. SWNT devices were assembled from tubes with different diameters in the range 0.7-1.5 nm. They emit light in the visible spectrum with peaks at 1.4 and 1.8 eV. Similar peaks are observed For MWNT and FLG devices. We propose that this light emission is due to phonon-assisted radiative decay from populated pi* band states at the M point to the Fermi level at the K point. Since for most carbon nanotubes as well as for graphene the energy of unoccupied states at the M point is close to 1.6 eV, the observation of two emission peaks at similar to 1.6 +/- similar to 0.2 eV could indicate radiative decay under emission or absorption of optical phonons, respectively.