• 文献标题:   Attached beta-cyclodextrin/gamma-(2,3-epoxypropoxy) propyl trimethoxysilane to graphene oxide and its application in copper removal
  • 文献类型:   Article
  • 作  者:   YU ZX, CHEN Q, LV L, PAN Y, ZENG GY, HE Y
  • 作者关键词:   betacyclodextrin, adsorption, copper ion, graphene oxide, removing
  • 出版物名称:   WATER SCIENCE TECHNOLOGY
  • ISSN:   0273-1223 EI 1996-9732
  • 通讯作者地址:   Southwest Petr Univ
  • 被引频次:   2
  • DOI:   10.2166/wst.2017.045
  • 出版年:   2017

▎ 摘  要

The environmental applications of graphene oxide and beta-cyclodextrin (beta-CD) have attracted great attention since their first discovery. Novel nanocomposites were successfully prepared by using an esterification reaction between beta-cyclodextrin/gamma-(2,3-epoxypropoxy) propyl trimethoxysilane grafted graphene oxide (beta-CD/GPTMS/GO). The beta-CD/GPTMS/GO nanocomposites were used to remove the Cu2+ from aqueous solutions. The characteristics of beta-CD/GPTMS/GO were detected by scanning electron microscopy (SEM), Fourier transform infrared, X-ray diffraction (XRD), thermogravimetric analysis (TG) and energy dispersive X-ray (EDX). The dispersibility of graphene oxide was excellent due to the addition of beta-CD. The adsorption isotherms data obtained at the optimum pH 7 were fitted by Langmuir isotherm model. The excellent adsorption properties of beta-CD/GPTMS/GO for Cu2+ ions could be attributed to the apolar cavity structure of beta-CD, the high surface area and abundant functional groups on the surface of GO. The adsorption patterns of beta-CD/GPTMS/GO were electrostatic attraction, formation of host-guest inclusion complexes and the ion exchange adsorption. The efficient adsorption of beta-CD/GPTMS/GO for Cu2+ ions suggested that these novel nanocomposites may be ideal candidates for removing other cation pollutants from waste water.