• 文献标题:   Synthesis and characterization of conductive copper-based metal-organic framework/graphene-like composites
  • 文献类型:   Article
  • 作  者:   ALFE M, GARGIULO V, LISI L, DI CAPUA R
  • 作者关键词:   composite material, organometallic compound, microporous material, nanostructure, electrical characterisation
  • 出版物名称:   MATERIALS CHEMISTRY PHYSICS
  • ISSN:   0254-0584 EI 1879-3312
  • 通讯作者地址:   CNR
  • 被引频次:   19
  • DOI:   10.1016/j.matchemphys.2014.06.015
  • 出版年:   2014

▎ 摘  要

Metal-organic framework (MOP) incorporating conductive graphene-like layers were synthesized and characterized. The selected MOF, HKUST-1, combines high surface area, water stability, simple preparation and low costs. Graphene-like layers incorporated into the MOF structure were obtained by a two-step oxidation/reduction wet treatment of a high surface carbon black. MOF composites were produced at different carbonaceous layers content. It was shown, through a wide characterization of the samples, that the composites preserve the main features of the parent MOF, additional exhibiting a tunable electrical conductivity. (C) 2014 Elsevier B.V. All rights reserved.