• 文献标题:   Graphite furnace atomic absorption spectrometric determination of vanadium after cloud point extraction in the presence of graphene oxide
  • 文献类型:   Article
  • 作  者:   LOPEZGARCIA I, MARINHERNANDEZ JJ, HERNANDEZCORDOBA M
  • 作者关键词:   vanadium, graphene oxide, cloud point extraction, graphite furnace atomic absorption, speciation
  • 出版物名称:   SPECTROCHIMICA ACTA PART BATOMIC SPECTROSCOPY
  • ISSN:   0584-8547
  • 通讯作者地址:   Univ Murcia
  • 被引频次:   7
  • DOI:   10.1016/j.sab.2018.02.013
  • 出版年:   2018

▎ 摘  要

Vanadium (V) and vanadium (IV) in the presence of a small concentration of graphene oxide (0.05 mg mL(-1)) are quantitatively transferred to the coacervate obtained with Triton X-l14 in a cloud point microextraction process. The surfactant-rich phase is directly injected into the graphite atomizer of an atomic absorption spectrometer. Using a 10-mL aliquot sample and 150 mu L of a 15% Triton X-114 solution, the enrichment factor for the analyte is 103, which results in a detection limit of 0.02 mu g L-1 vanadium. The separation of V(V) and V(IV) using an ion-exchanger allows speciation of the element at low concentrations. Data for seven reference water samples with certified vanadium contents confirm the reliability of the procedure. Several beer samples are also analyzed, those supplied as canned drinks showing low levels of tetravalent vanadium. (C) 2018 Elsevier B.V. All rights reserved.