▎ 摘　　要

A polylysine/graphene modified electrode was prepared. The electrochemical behaviour of diethylstilbestrol on the surface of this electrode was studied. A new method for the direct determination of diethylstilbestrol in food was developed. The experimental results showed that there was a pair of reversible redox peaks for diethylstilbestrol on this modified electrodes in 0.5 similar to 1.0 V range in a phosphate buffer solution (pH 3.0). Compared with the effects of a glassy carbon electrode and a polylysine modified electrode, it was concluded that the polylysine/graphene modified electrode has a higher electrocatalytic effect on the oxidation of diethylstilbestrol. In the range of 8.00x 10(-8) similar to 1.00x 10(-5) mol/L, the concentration of diethylstilbestrol was directly proportional to its oxidation peak current, and the detection limit is 1.20 x10(-9) mol/L. The relative standard deviation ( RSD ) was 1.7% over six parallel tests. The modified electrode had a high sensitivity and good selectivity and better stability than the control electrode and could be used to determine the concentration of diethylstilbestrol in beef, mutton and milk with recovery rates of 97.0% similar to 103.0%.