• 文献标题:   Preparation of multi-layer graphene on nickel-coated silicon microchannel plates by a hydrothermal carbonization procedure and its improved field emission properties
  • 文献类型:   Article
  • 作  者:   WU DJ, ZHANG C, LIANG C, ZHU YP, XU SH, XIONG DY, XUE SL, WANG LW, CHU PK
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY C
  • ISSN:   2050-7526 EI 2050-7534
  • 通讯作者地址:   E China Normal Univ
  • 被引频次:   17
  • DOI:   10.1039/c5tc03993b
  • 出版年:   2016

▎ 摘  要

An emission cell comprising multi-layer graphene (MLG) on nickel-coated silicon microchannel plates (Ni/Si-MCPs) was prepared. The Ni3C film was formed on the Si-MCPs by hydrothermal carburization in a polyol solution containing a small amount of NaAc as the carbon source and thermal annealing was performed to produce the vertically and horizontally aligned multi-layer graphene field-emission cathode on the surface of the Ni/Si-MCPs (MLG-MCPs). The microstructure and surface morphology were investigated and field emission (FE) studies indicated that the MLG-MCPs delivered better FE performance than Ni/Si-MCPs due to characteristics such as sharp edges, large aspect ratio, and the vertically and horizontally aligned and patterned MLG with good electrical conductivity. The turn-on field of the sample annealed at 800 degrees C was 2.0 V mu m(-1) at a current density of 10 mu A cm(-2) and the field emission threshold was 3.2 V mu m(-1) at 1 mA cm(-2). The structure was very stable showing 97.5% retention after continuous operation for over 6 h at 2 x 10(-5) Pa, suggesting a promising candidate for FE devices. This would open up possibilities for the next generation FE electron sources from well-aligned macroporous graphene with skeleton and extend their practical applications.