• 文献标题:   Pressure-induced chemical enhancement in Raman scattering from graphene-Rhodamine 6G-graphene sandwich structures
  • 文献类型:   Article
  • 作  者:   LEE Y, KIM H, LEE JB, CHO JH, AHN JH
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   A440 Engn Bldg 1
  • 被引频次:   8
  • DOI:   10.1016/j.carbon.2015.03.065
  • 出版年:   2015

▎ 摘  要

In this study, we introduce a new method to enhance the Raman signals of a graphene-Rhodamine 6G (R6G)-graphene sandwich structure by creating a magnet-induced static pressure to maximize the chemical contact between the R6G molecules and graphene. The increase in pressure in the graphene-R6G-graphene sandwich geometry plays a crucial role in enhancing the Raman signal by approximately up to 30 times in comparison to that acquired from a R6G/graphene layered film. In addition, the pressure-induced enhancement effects in the planar vibrational motion of the R6G (1200-1500 cm(-1)) were more recognizable than those in the low-wavenumber region and were almost comparable to the surface-induced enhancement effects in the Raman scattering signals observed from the spontaneously formed 'folded' pseudo-pi-bonded graphene-R6G-graphene sandwich structures. The enhancement effect diminished with an increase in the number of graphene layers (on the bottom side), which was clearly discernible when graphene/glass sandwiched structures placed on top of exfoliated multilayered graphene coated with R6G were imaged. (C) 2015 Elsevier Ltd. All rights reserved.