• 文献标题:   One-step electrochemical preparation of graphene-based heterostructures for Li storage
  • 文献类型:   Article
  • 作  者:   ZHANG WY, ZENG Y, XIAO N, HNG HH, YAN QY
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY
  • ISSN:   0959-9428 EI 1364-5501
  • 通讯作者地址:   Nanyang Technol Univ
  • 被引频次:   50
  • DOI:   10.1039/c2jm16315b
  • 出版年:   2012

▎ 摘  要

We report a facile method to prepare nanoarchitectured metal oxides/graphene hybrids as both positive and negative electrodes for Li-ion batteries. The metal oxides/graphene hybrids were synthesized by deposition of metal oxides and exfoliation of graphene sheets in a one-step electrochemical process. The hybrid electrodes showed high specific capacities with excellent cycling stability. For example, the Fe2O3/graphene anode was able to deliver a discharge capacity of up to 894 mA h g(-1) during the 50th cycle at 0.3 C. Co3O4/graphene depicted a discharge capacity of 880 mA h g(-1) during the 40th cycle at 0.3 C. The V2O5/graphene cathode delivered a discharge capacity of 208 mA h g(-1) during the 100th cycle at 6.8 C.