• 文献标题:   Stability and Reactivity of Graphene-Templated Nanoclusters
  • 文献类型:   Article
  • 作  者:   GERBER T, GRANAS E, SCHRODER UA, STRATMANN P, SCHULTE K, ANDERSEN JN, KNUDSEN J, MICHELY T
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447
  • 通讯作者地址:   Univ Cologne
  • 被引频次:   4
  • DOI:   10.1021/acs.jpcc.6b07828
  • 出版年:   2016

▎ 摘  要

Exploiting the versatility of the graphene/Ir(111) template, we performed a comparative study on arrays of various metallic nanoclusters. Using scanning tunneling microscopy and synchrotron-based high-resolution X-ray photoelectron spectroscopy, we investigated the size dependent stability of Pt, Ir, and Au nanoclusters against sintering upon gas exposure. These clusters display gross differences in their gas adsorption properties, as well as in their activity for the CO oxidation reaction.