• 文献标题:   Dopamine sensor based on a glassy carbon electrode modified with a reduced graphene oxide and palladium nanoparticles composite
  • 文献类型:   Article
  • 作  者:   PALANISAMY S, KU SH, CHEN SM
  • 作者关键词:   reduced graphene oxide, palladium nanoparticle, dopamine, electrochemical oxidation, sensor
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Natl Taipei Univ Technol
  • 被引频次:   116
  • DOI:   10.1007/s00604-013-1028-1
  • 出版年:   2013

▎ 摘  要

We report on a sensitive electrochemical sensor for dopamine (DA) based on a glassy carbon electrode that was modified with a nanocomposite containing electrochemically reduced graphene oxide (RGO) and palladium nanoparticles (Pd-NPs). The composite was characterized by scanning electron microscopy, energy dispersive spectroscopy, and electrochemical impendence spectroscopy. The electrode can oxidize DA at lower potential (234 mV vs Ag/AgCl) than electrodes modified with RGO or Pd-NPs only. The response of the sensor to DA is linear in the 1-150 mu M concentration range, and the detection limit is 0.233 mu M. The sensor was applied to the determination of DA in commercial DA injection solutions.