• 文献标题:   Raman and infrared properties and layer dependence of the phonon dispersions in multilayered graphene
  • 文献类型:   Article
  • 作  者:   JIANG JW, TANG H, WANG BS, SU ZB
  • 作者关键词:  
  • 出版物名称:   PHYSICAL REVIEW B
  • ISSN:   1098-0121
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   57
  • DOI:   10.1103/PhysRevB.77.235421
  • 出版年:   2008

▎ 摘  要

The symmetry group analysis is applied to classify the phonon modes of N-stacked graphene layers (NSGLs) with AB and AA stacking, particularly their infrared and Raman properties. The dispersions of various phonon modes are calculated in a multilayer vibrational model, which is generalized from the lattice vibrational potentials of graphene to including the interlayer interactions in NSGLs. The experimentally reported redshift phenomena in the layer-number dependence of the intralayer optical C-C stretching mode frequencies are interpreted. An interesting low-frequency interlayer optical mode is revealed to be Raman or infrared active in even or odd NSGLs, respectively. Its frequency shift is sensitive to the layer number and saturated at about 10 layers.