• 文献标题:   Suppressing spinodal decomposition by incorporation of reduced graphene oxide into (Sn0.5Ti0.5)O-2 solid solution
  • 文献类型:   Article
  • 作  者:   CHOI YH
  • 作者关键词:   sno2tio2, reduced graphene oxide, solid solution, spinodal decomposition, phase separation
  • 出版物名称:   MATERIALS RESEARCH EXPRESS
  • ISSN:   2053-1591
  • 通讯作者地址:   Daegu Catholic Univ
  • 被引频次:   0
  • DOI:   10.1088/2053-1591/ab7c23
  • 出版年:   2020

▎ 摘  要

Here, it is found that the incorporation of rGO into (Sn0.5Ti0.5)O-2 solid solution suppresses spinodal decomposition via two characteristic routes. First, the addition of rGO to the solid solution leads to the compositional change from (Sn0.5Ti0.5)O-2 to (Sn0.1Ti0.9)O-2 moving out of the miscibility gap at SnO2-TiO2 phase diagram, which suppresses spinodal decomposition. The results indicate that addition of rGO promotes reduction and evaporation of SnO2 during heat treatment. Secondly, the incorporation of rGO is found to produce the solid solution with lower Sn and Ti valences and more oxygen vacancies, which can also suppress spinodal decomposition.