• 文献标题:   Preparation of Graphene-Like Porous Carbons With Enhanced Thermal Conductivities From Lignin Nano-particles by Combining Hydrothermal Carbonization and Pyrolysis
  • 文献类型:   Article
  • 作  者:   DONG HL, LI M, JIN YC, WU Y, HUANG CX, YANG JL
  • 作者关键词:   lignin nanoparticle, porous carbon, thermal conductivity, hydrothermal carbonization, graphene
  • 出版物名称:   FRONTIERS IN ENERGY RESEARCH
  • ISSN:   2296-598X
  • 通讯作者地址:   Nanjing Forestry Univ
  • 被引频次:   4
  • DOI:   10.3389/fenrg.2020.00148
  • 出版年:   2020

▎ 摘  要

Lignin nano-particles (LNPs) exhibit properties that distinguish them from the production of other lignin-based materials. However, little research has been performed to investigate whether porous carbons produced from LNPs exhibit a performance superior to those derived from untreated lignin. In this study, lignin was fabricated into LNPs and used to prepare high-performance porous carbons with enhanced thermal conductivities compared to that of carbons from neat lignin. Two different preparation protocols were employed: direct pyrolysis and hydrothermal carbonization followed by pyrolysis. Carbons obtained from 100 to 300 nm LNPs possessed more graphene-like structures than carbons from unaltered lignin. In addition, carbons prepared using a combination of hydrothermal carbonization and pyrolysis exhibited higher specific surface areas (108.81-220.75 m(2)/g) and total pore volumes (0.098-0.166 cm(3)/g) than those prepared via direct pyrolysis. In addition, LNP-derived carbons exhibited superior thermal conductivities (0.45 W/mK) and thermal conductivity rates (0.51 degrees C/s). This work provides the useful finding that superior graphene-like porous carbons can be produced by transforming lignin into LNP and then hydrothermally carbonizing the resulting material prior to pyrolysis.