• 文献标题:   In situ synthesized SnO2 nanorod/reduced graphene oxide low-dimensional structure for enhanced lithium storage
  • 文献类型:   Article
  • 作  者:   ZHANG W, XIAO XZ, ZHANG YW, LI JP, ZHONG JY, LI M, FAN XL, WANG CT, CHEN LX
  • 作者关键词:   lithiumion batterie, sno2based, nanorod, in situ, electrochemical, graphene
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   3
  • DOI:   10.1088/1361-6528/aaa72c
  • 出版年:   2018

▎ 摘  要

A unique SnO2 nanorod (NR)/reduced graphene oxide (RGO) composite morphology has been synthesized using the in situ hydrothermal method, for use as an anode material in lithium-ion batteries. The SnO2 NR adhering to the RGO exhibits a length of 250-400 nm and a diameter of 60-80 nm without any obvious aggregation. The initial discharge/charge capacities of the SnO2 NR/RGO composite are 1761.3 mAh g(-1) and 1233.1 mAh g(-1), with a coulombic efficiency (CE) of 70% under a current density of 200 mA g(-1), and a final capacity of 1101 mAh g(-1) after 50 cycles. The rate capability of the SnO2 NR/RGO is also improved compared to that of bare SnO2 NR. The superior electrochemical performance is ascribed to the special morphology of the SnO2 NRs-which plays a role in shorting the transmission path- and the sheet-like 2D graphene, which prevents the agglomeration of SnO2 and enhances conductivity during the electrochemical reaction of SnO2 NR/RGO.