• 文献标题:   Preparation and characterization of platinum (Pt) and palladium (Pd) nanoparticle decorated graphene sheets and their utilization for the elimination of basic fuchsin and indigo carmine dyes
  • 文献类型:   Article
  • 作  者:   KURT BZ, DURMUS Z, DURMUS A
  • 作者关键词:   graphene, noble metal nanoparticle, nanocomposite, antioxidant activity, photocatalytic degradation
  • 出版物名称:   SOLID STATE SCIENCES
  • ISSN:   1293-2558 EI 1873-3085
  • 通讯作者地址:   Bezmialem Vakif Univ
  • 被引频次:   7
  • DOI:   10.1016/j.solidstatesciences.2015.11.012
  • 出版年:   2016

▎ 摘  要

In this study, graphene nano sheets, prepared with chemical oxidation and reduction routes via modified-Hummer method, were successfully decorated with platinum (Pt) and palladium (Pd) nanoparticles. Structural and morphological features of resulted graphene-metal nanocomposites were characterized with FT-IR, XRD, SEM and TEM methods. Anti-oxidant activity (AOA) values of nanocomposites were determined. The IC50 values of Pt-graphene and Pd-graphene nanocomposites were found to be 46.1 and 90.2 mg/mL, respectively based on the ABTS method and 80.2 and 143.7 mg/mL according to the DPPH method. It was found that the graphene-metal nanocomposites exhibited superior free radical scavenging activity compared to several types of noble metal nano particles although the nanocomposites consist of much lower amount of active metal sites than the nano-crystalline metal powders. It was consequently reported that the graphene-metal nanocomposites could be successfully used for the photocatalytic elimination of fuchsin and indigo carmine dyes under light irradiation. (C) 2015 Elsevier Masson SAS. All rights reserved.