• 文献标题:   In-situ polymerization of polyaniline on the surface of graphene oxide for high electrochemical capacitance
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   LI XL, ZHONG QN, ZHANG XL, LI TT, HUANG JM
  • 作者关键词:   polyaniline, graphene oxide, nanocomposite, supercapacitor
  • 出版物名称:   THIN SOLID FILMS
  • ISSN:   0040-6090
  • 通讯作者地址:   Chongqing Univ
  • 被引频次:   24
  • DOI:   10.1016/j.tsf.2015.01.055
  • 出版年:   2015

▎ 摘  要

Conducting polymer polyaniline (PANI) was in-situ polymerized on the surface of graphene oxide (GO) to form PANI encapsulating GO nanocomposites. The morphology and microstructure were examined by scanning electron microscopy, X-ray diffraction and N-2 absorption/desorption analysis. Electrochemical properties were tested by cyclic voltammetry, galvanostatic charge/discharge cycles and electrochemical impedance spectroscopy. Experimental results showed that ethanol assisted the dispersion of GO in water and facilitated the diffusion of polymer monomers on GO. GO as a support material can provide sufficient reaction sites for the deposition of aniline to form the film-like GO/PANI composites. Capacitive performance illustrated that the in-situ polymerization of PANI on GO was effective in improving the specific capacitance and cycling stability. (C) 2015 Elsevier B.V. All rights reserved.