• 文献标题:   Copper Nanowire-Graphene Core-Shell Nanostructure for Highly Stable Transparent Conducting Electrodes
  • 文献类型:   Article
  • 作  者:   AHN Y, JEONG Y, LEE D, LEE Y
  • 作者关键词:   copper nanowire, graphene, coreshell, transparent conducting electrode, polymer solar cell
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   DGIST
  • 被引频次:   110
  • DOI:   10.1021/acsnano.5b00053
  • 出版年:   2015

▎ 摘  要

A copper nanowire-graphene (CuNW-G) core-shell nanostructure was successfully synthesized using a low-temperature plasma-enhanced chemical vapor deposition process at temperatures as low as 400 degrees C for the first time. The CuNW-G core-shell nanostructure was systematically characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Raman, and X-ray photoelectron spectroscopy measurements. A transparent conducting electrode (ICE) based on the CuNW-G core-shell nanostructure exhibited excellent optical and electrical properties compared to a conventional indium tin oxide TCE. Moreover, it showed remarkable thermal oxidation and chemical stability because of the tight encapsulation of the CuNW with gas-impermeable graphene shells. The potential suitability of CuNW-G ICE was demonstrated by fabricating bulk heterojunction polymer solar cells. We anticipate that the CuNW-G core-shell nanostructure can be used as an alternative to conventional TCE materials for emerging optoelectronic devices such as flexible solar cells, displays, and touch panels.