• 文献标题:   Cobalt oxyhydroxide/graphene oxide nanocomposite for amelioration of electrochemical performance of lithium/sulfur batteries
  • 文献类型:   Article
  • 作  者:   SEYYEDIN ST, YAFTIAN MR, SOVIZI MR
  • 作者关键词:   lithium/sulfur battery, sheet like structure, metal oxyhydroxide, sulfur cathode
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:   Univ Zanjan
  • 被引频次:   7
  • DOI:   10.1007/s10008-016-3411-4
  • 出版年:   2017

▎ 摘  要

Cobalt oxyhydroxide combination with graphene oxide (CoOOH@GO) as a novel conductive matrix is developed for high performance lithium/sulfur batteries. Enhancement retention of polysulfide species into matrix of cobalt oxyhydroxide anchored on graphene oxide flakes by strong chemical binding of carbon-sulfur is demonstrated. Sulfur incorporated in the sheet-like morphology of CoOOH@GO delivers high initial discharge specific capacity of 1190.85 mAh/g, which raises 260 mAh/g with respect to graphene oxide/sulfur (GO/S) as a cathode material. Furthermore, CoOOH@GO/S maintains the average coulombic efficiency of 96 % after 300 cycles at 1 C rate with capacity retention of about 61 %. Good current rate capability of CoOOH@GO/S cathode reveals that the resulting composite is open platform for electrolyte diffusion and fast ion transportation leading to the improved electrochemical performance of lithium/sulfur batteries.