• 文献标题:   Coupling graphene microribbons with carbon nanofibers: New carbon hybrids for high-performing lithium and potassium-ion batteries
  • 文献类型:   Article
  • 作  者:   TUNG TT, MOUSSA M, TRIPATHI KM, KIM T, NINE MJ, NANJUNDAN AK, DUBAL D, LOSIC D
  • 作者关键词:   hybrid carbon, graphene miroribbon, graphene fiber, li batterie, potassium batterie
  • 出版物名称:   SUSTAINABLE MATERIALS TECHNOLOGIES
  • ISSN:   2214-9937
  • 通讯作者地址:  
  • 被引频次:   11
  • DOI:   10.1016/j.susmat.2022.e00393 EA APR 2022
  • 出版年:   2022

▎ 摘  要

Carbon-carbon allotropic hybrids exhibit remarkable properties, including exceptional electrochemical charge storage capacities. A novel hybrid material composed of 1D carbon nanofibers (CNF) and 2D graphene micro -ribbons (GMR) was synthesized and incorporated as anodes in Li-ion batteries (LIB) and Potassium-ion batte-ries (KIB) for improved storage capacity. CNF-GMR material was hybridized simultaneously by one-step chemical vapour deposition (CVD) synthetic process, wherein the CNF were grown on the graphene surface using an iron oxide catalyst. Meanwhile, the GMRs were formed by the catalytic cutting of few-layer graphene. This unique carbon-carbon allotropic hybrid exhibits excellent structural integrity, good electrical conductivity (718 S/m) and high specific surface area (305.6 g/m(2)). The as-prepared materials, when used as an anode in batteries, exhibited a highly reversible capacity (598 mAhg(-1) and 410 mAhg(-1) at 0.10 Ag-1 for LIB and KIB, respectively) with fast charging and discharging capability, and long-term cycling stability with 99% Coulombic efficiency over 1000 cycles.