• 文献标题:   Imprinted propyl gallate electrochemical sensor based on graphene/single walled carbon nanotubes/sol-gel film
  • 文献类型:   Article
  • 作  者:   XU GL, CHI Y, LI L, LIU SH, KAN XW
  • 作者关键词:   imprinted solgel electrochemical sensor, graphene, single walled carbon nanotube, propyl gallate
  • 出版物名称:   FOOD CHEMISTRY
  • ISSN:   0308-8146 EI 1873-7072
  • 通讯作者地址:   Anhui Normal Univ
  • 被引频次:   15
  • DOI:   10.1016/j.foodchem.2014.12.097
  • 出版年:   2015

▎ 摘  要

A novel imprinted sol-gel electrochemical sensor for the determination of propyl gallate (PG) was developed based on a composite of graphene and single walled carbon nanotubes (GR-SWCNTs). It was fabricated by stepwise modifying GR-SWCNTs and molecularly imprinted polymers and stored in 0.10 mol L-1 phosphate buffer solution pH 6.0, which endowed the sensor good sensitivity and selective recognition towards template molecules. The morphology and specific adsorption capacity of the sensor was characterized by scanning electron microscope and electrochemical methods, respectively. Under the optimized conditions, a linear range of the sensor to PG was 8.0 x 10(-8)-2.6 x 10(-3) mol L-1 with a limit of detection of 5.0 x 10(-8) mol L-1 (S/N = 3). The sensor exhibited specificity and selectivity towards template molecules as well as excellent reproducibility, regeneration and stability. Furthermore, the sensor could be applied to determine PG in edible oils, instant noodles and cookies with satisfactory results. (C) 2015 Elsevier Ltd. All rights reserved.