• 文献标题:   Electrical Conductivity and Ferromagnetism in a Reduced Graphene-Metal Oxide Hybrid
  • 文献类型:   Article
  • 作  者:   KARIM MR, SHINODA H, NAKAI M, HATAKEYAMA K, KAMIHATA H, MATSUI T, TANIGUCHI T, KOINUMA M, KUROIWA K, KURMOO M, MATSUMOTO Y, HAYAMI S
  • 作者关键词:   graphene, graphene oxide, ferromagnetism, conductivity, hybrid material
  • 出版物名称:   ADVANCED FUNCTIONAL MATERIALS
  • ISSN:   1616-301X EI 1616-3028
  • 通讯作者地址:   Kumamoto Univ
  • 被引频次:   43
  • DOI:   10.1002/adfm.201201418
  • 出版年:   2013

▎ 摘  要

The rare coexistence of ferromagnetism and electrical conductivity is observed in the reduced graphene oxidemetal oxide hybrids, rGO-Co, rGO-Ni, and rGO-Fe, using chemical reduction with hydrazine or ultraviolet photoirradiation of the graphene oxidemetal complexes, GO-Co, GO-Ni, and GO-Fe. The starting and final materials are characterized by X-ray photoelectron spectroscopy, transmission electron microscopy (TEM), elemental analysis, Mossbauer spectroscopy, and Raman spectroscopy. In contrast to graphene, where the electrical conductivity and magnetic properties are controlled by carrier (electron or hole) doping, those of graphene oxide can be controlled by complexation with Co2+, Ni2+, and Fe3+ cations through the strong electrostatic affinity of negatively charged graphene oxide towards metal cations. The presence of ferromagnetism and electrical conductivity in these hybrids can promote significant applications including magnetic switching and data storage.